Latest Buzz...
                  

Translate

Wednesday, March 25, 2015

Fossil fuels, asbestos, lead and white phosphorus

The beginning of the fossil fuel era

1882 [Thomas Edison]
Edison's work led to the first commercial power plant in 1882.

1903 [Charles Curtis]
The first steam turbine generator, pioneered by Curtis, was put into operation at the Newport Electric Corporation in Newport, Rhode Island.
.
.
.
.
.

Asbestos related diseases

Although the health risks associated with asbestos had been long observed and were confirmed scientifically early in the Twentieth Century, it was not until the 1970s that the Australian community was made aware of the problem.

Asbestos was phased out in Australia after 1980. It was finally banned from building products in 1989, though it remained in gaskets and brake linings until recently. Asbestos was prohibited completely after 31 December 2003, and can not be imported, used or recycled.

Asbestos is a fibrous mineral that was widely used in Australia in the 20th Century for many industrial and domestic applications.

Inhalation of asbestos fibres has been shown to lead to a number of serious health risks, including asbestosis and the cancer mesothelioma.

As these can take a number of decades to develop, it is likely that the effects on the Australian community of exposure to asbestos will continue to increase into the 21st Century.


Lead alert facts: Lead in house paint

Before 1970, paints containing high levels of lead were used in many Australian houses. Exposure to lead is a health hazard. Even small amounts of dust or chips of paint containing lead, generated during minor home repairs, can be a health risk.

Lead in domestic paint has declined from 50% before 1965, to 1% in 1965. In 1992, it was reduced to 0.25%, and in 1997 it was further reduced to 0.1%.

On Catalyst: could lead exposure in childhood lead to an adult life marked by violent crime?

Any house painted before 1970 is likely to contain leaded paint
Any house painted before 1970 is likely to contain leaded paint
"We've undertaken similar studies in Australia which show a very strong relationship between lead in air and crime 22 years later."

The beginning of the white phosphorus match era until the final ban

1830 [Charles Sauria]
The U.S. Congress passed a law placing a prohibitively high tax on them in 1913.
Sauria formulated a match using white phosphorus. However, the phosphorus was deadly. Many people developed a disorder known as 'phossy jaw'. Children who sucked on matches developed skeletal deformities. Phosphorus factory workers got bones diseases. One pack of matches contained enough phosphorus to kill a person.  Deaths and suicides from eating the heads of matches became frequent.

Ripper Street- A case of Phossy  Jaw, in it’s worst stages.
True horror story - A case of Phossy  Jaw, in it’s worst stages.
1838 [The first case of "phossy jaw" was recorded]
The victim, a female Viennese matchstick maker, had been exposed to the phosphorous vapors over a five-year period. The average time between exposure to the phosphorous vapors and the appearance of "phossy jaw" was about five years, but only about 5% of those exposed were inflicted with this disfiguring and often lethal affliction

The infamous "phossy jaw" became an epidemic of exposed bone osteonecrosis exclusively in the jaws began around 1838. This epidemic of osteonecrosis produced pain, swelling, debilitation, and a reported mortality of 20% and was linked to "yellow phosphorous," the key ingredient in "strike-anywhere" matches. In match-making factories, workers called "mixers," "dippers," and "boxers" were exposed to heated fumes containing this compound. Related to the duration of exposure, many of these workers developed painful exposed bone in the mouth, whereas their office-based counterparts did not.

1888 [the “London matchgirls” strike]
Phossy jaw, also known as phosphorus necrosis of the jaw, was most commonly seen among match workers in the 19th and early 20th centuries – famously, the “London matchgirls,” whose strike of 1888 brought the problem into the public eye – fifty years after the first recorded case.
 
In those days, matches were made with white phosphorus, and prolonged exposure to the vapor of the substance caused deposits to form in the victims’ jawbones. Throbbing toothaches, extreme swelling of the gums and abscesses in the jawbone followed. The afflicted bones would also take on a green-white tinge, while severe brain damage also lay in wait for those already suffering.

The only known treatment was to surgically remove the jawbones; if it were left unchecked, organ failure and death would result. The disease also caused tremendous pain and disfigurement, and the rotting bone tissue emitted a putrid-smelling discharge. Phossy jaw did not begin to decline until 1906 – sixty eight years after the first recorded case.

1872 [Bans commence on white phosphorus matches]
Finland prohibited the use of white phosphorus in 1872, followed by Denmark in 1874, France in 1897, Switzerland in 1898, and the Netherlands in 1901.

1898 [Henri Savene and Emile David Cahen]
Two French chemists, Henri Savene and Emile David Cahen, developed a safe match using phosphorus sesquisulfide that was patented in 1898. They proved that the substance was not poisonous, that it could be used in a "strike-anywhere" match, and that the match heads were not explosive. They patented a safety match composition in 1898 based on phosphorus sesquisulfide and potassium chlorate.

1906 [International Agreement to ban white phosphorus in matches]
An agreement, the Berne Convention, was reached at Bern, Switzerland, in September 1906, which banned the use of white phosphorus in matches. This required each country to pass laws prohibiting the use of white phosphorus in matches. Great Britain passed a law in 1908 prohibiting its use in matches after 31 December 1910.

The United States did not pass a law to ban the manufacture and sale of white phosphorus matches, but instead Congress passed a law placing a prohibitively high tax on them in 1913.  This punitive tax on white phosphorus-based matches was sufficiently so high as to render their manufacture financially impractical.

India and Japan banned them in 1919; China followed, banning them in 1925 - five years before the centennial of the invention of white phosphorus matches.


Monday, March 16, 2015

Gambling on climate change - no safe bets

Gambling on Climate Change
Gambling on Climate Change

Lectures on the Global Warming Gamble 

Extract of -
The Global Warming Policy Foundation
2011 Annual GWPF Lecture
Westminster Cathedral Hall | 26 October 2011

One Christian Perspective on Climate Change
Cardinal George Pell
Archbishop of Sydney


Let me begin by thanking the Global Warming Policy Foundation for the invitation to deliver this lecture.

Why might a Catholic bishop comment?

We might ask whether my scepticism is yet another example of religious ignorance and intransigence opposing the forward progress of science as is alleged in the confrontations between Galileo and the Papacy in the early seventeenth century, when the Church party on the evidence of scripture insisted that the sun moved around the earth.

It is not generally realized that in 2001 at least, one of the IPCC Third Assessment Report’s Working Groups agreed: “In climate research and modelling, we are dealing with a coupled, non-linear, chaotic system, and therefore that the long-term prediction of future climate states is not possible”.

Arnold helped to explain why the systems around us work, how fluids flow. Like Lorenz, he found that small changes had an immense impact on outcomes. For him long-range weather forecasting was effectively impossible, because small events could have dramatic, unforeseen consequences.


A small event - dramatic, unforeseeable consequences

Changes in Carbon Dioxide and Temperature
Changes in Carbon Dioxide and Temperature (EPA)
Fluctuations in temperature (red line) and in the atmospheric concentration of carbon dioxide (yellow) over the past 649,000 years.
"SMALL" Change: The vertical red bar at the end is the increase in atmospheric carbon dioxide levels over the past two centuries and before 2007.
From "A brief history of the universe"

  • Human beings first arrived in Europe about 35,000 years ago.
  • The first cities were only built 8,800 years ago.

An observation on Cardinal Pell's Lecture

Cardinal Pell highlights key attributes of climate science that give little reason for comfort:
  • "In climate research and modelling, we are dealing with a coupled, non-linear, chaotic system, and therefore that the long-term prediction of future climate states is not possible" and
  • "small events could have dramatic, unforeseen consequences."
The implications of this description are perhaps a little obscure.

An example of a non-linear system is a house-of-cards. It is susceptible to sudden collapse when a single card is moved even though it is seemingly stable when other small changes are made. That is, small events can have dramatic, unforeseen consequences.

There are three unfortunate characteristics of such systems -
  • Very small changes can create completely unexpected and seemingly disproportionate changes with little warning.
  • Predicting behaviour of the system will be very difficult. 
  • Removing a "trigger" that seemingly precipitated a disproportionate change will most likely fail to restore the system to its previous state.

Monday, March 2, 2015

Electricity peak period pricing a poor idea

The Australian Energy Regulator processes data into a graph showing seasonal peak period demand in energy market regions.

Seasonal peak electricity demand (by region)
Seasonal peak electricity demand (by region)
An article by RMIT authors Yolande Strengers and Larissa Nicholls "Feral o'clock: why families struggle to shift their energy use" observes -
"A key plank of the Australian Government’s draft energy policy is to reform electricity pricing so that it more accurately reflects rises and falls in peak demand."
and -
"But research we have published today suggests that this policy focus is missing other opportunities to shift electricity demand. Research with parents reveals that many household routines are unlikely to shift in response to cost-reflective tariffs..."
When you drill down into the electricity demand data - summarised beyond recognition by the Australian Energy Regulator - you may well conclude that encouraging families to shift electricity demand is not only difficult. It is also pointless.

The strategy of demand-response players, such as EnerNOC, is far more precisely targeted at the underlying problem -
"Demand response allows energy users of all kinds to act as “virtual power plants,” adding stability to the grid by voluntarily lowering their demand for electricity. Participants in demand response programs get paid for providing demand response capacity..."
The "peak seasonal demand" for New South Wales in Summer 2012/2013 is shown by the Australian Energy Regulator to be about 14,000 megawatts (MW) during the peak 30 minute electricity market interval during December 2012 - February 2013.

Graphing the source data from the Australian Energy Market Operator for this period shows that peak demand rarely went above 10,000 megawatts. Promoters of time-of-use charging may want to install generating and network capacity to supply 40 percent more electricity - 14,000 megawatts - for one to two hours each summer, and earn a profit from this grossly excessive capital investment. EnerNOC has got the right approach: pay a few electricity users to turn off discretionary plant and equipment for one or two hours each summer, and save the extravagant wasted investment.













Monday, February 16, 2015

A spoonful of sunshine makes the demand for coal go down

The University of Minnesota Solar Energy Laboratory develops technology using concentrated solar radiation for fuel and chemical production. It provided the inspiration for this article.


"In traditional biomass gasification, 20 to 30 percent of the biomass feedstock is burned to produce heat for the process. But if the required thermal energy is supplied from a concentrated solar source, all of the biomass can be converted into useful synthesis gas." (Read more...)

Burning any carbon-containing hydrocarbon or carbohydrate fuel - whether it is biomass or coal - uses some energy to break the chemical bonds that bind the atoms together in the molecules of the fuel and then releases some energy when those atoms combine with oxygen to produce carbon dioxide and water vapour.

Solar gasification of biomass: design and characterization of a molten salt gasification reactor

by Hathaway, Brandon Jay (2013)
A former doctoral student, Brandon Hathaway is now the lead research scientist at the University of Minnesota Solar Energy Laboratory.
"The reactor developed in this work allows for 3 kWth operation with an average aperture flux of 1530 suns at salt temperatures of 1200 K with pneumatic injection of ground or powdered dry biomass feedstocks directly into the salt melt." (Read more...)
Link to Dr Hathaway on Twitter

Here is a diagram that represents the energy used and released by burning brown coal mined in the Gippsland Basin coal fields  of Victoria, Australia:

Burning hydrocarbons and carbohydrates - energy used and released

What the diagram represents is that 1 kilogram (2.2 lbs) of brown coal is decomposed into carbon monoxide and hydrogen by absorbing 5.54 megajoules of heat energy. 

The resulting carbon monoxide and hydrogen then releases 14.14 megajoules of heat energy when it combines with oxygen to produce carbon dioxide and water vapour.

The net heat energy available from burning this kilogram of brown coal is the difference between these two energy flows: 14.14 - 5.54 = 8.60 megajoules of heat energy.

Burning a kilogram of brown coal in a coal-fired power station allows a proportion of this 8.60 megajoules of heat energy to be converted to electricity.  Typically only about 40 percent is delivered as electricity: around 0.96 kilowatt-hours.

A different way of converting brown coal to electricity enables a far greater amount of electricity to be produced from each kilogram:
  • First each kilogram of brown coal is decomposed into carbon monoxide and hydrogen by absorbing 5.54 megajoules of concentrated solar thermal energy.  
  • Second, the resulting carbon monoxide and hydrogen releases 14.14 megajoules of heat energy when it combines with oxygen to produce carbon dioxide and water vapour in a gas power plant. Typically about 60 percent is delivered as electricity: around 2.36 kilowatt-hours.

The coal needed to produce 0.96 kilowatt-hours of electricity is reduced from 1 kilogram (2.2 lbs) to just 405 grams (14.3 ozs).

Tuesday, February 10, 2015

Mega-power plant planned

Raras Cahyafitri, The Jakarta Post, Jakarta | Headlines | Fri, November 07 2014

Indonesia will build a 5,000-megawatt power plant in Cilacap, Central Java, as part of the new government’s ambitious program to have at least an additional 35,000 MW of power within five years.

Coordinating Maritime Affairs Minister Indroyono Soesilo said Thursday that development of the first stage of the huge power plant complex, which would be among the largest in the world, was expected to begin next year so that it could begin commercial operation by 2018. 

“In the first stage, the power generation capacity will reach 2,000 MW,” he said after a coordinating meeting with relevant institutions at the office of the Energy and Mineral Resources Ministry. Indroyono said the entire power plant project, which will have five generation units each with 1,000-MW capacity, was expected to be completed within seven years.
Adaro Energy is planning to expand its power generation business to tap Indonesia's growing demand for electricity.
Adaro Energy is planning to expand its power generation business
to tap Indonesia's growing demand for electricity.

Faced with falling demand for coal, producers build inefficient coal power stations


The minister said the power plant complex would be built by PT Jawa Energy and backed by Chinese investors.

If it is realized, the new power plant will be the largest in Indonesia. The coal-fired Paiton power plant in Probolinggo, East Java, which at present produces about 2,000 MW of electricity, is the country’s largest. The Paiton power plant was initially designed to have a total capacity of more than 4,000 MW. 

Taiwan’s Taichung is the largest coal-fired power plant in the world, with a capacity of 5,500 MW. 

Energy and Mineral Resources Minister Sudirman Said explained that the 5,000-MW power plant would use an ultra-super critical boiler technology that would be able to reduce the harmful emissions resulting from coal usage.

“The power produced will first be directed to an industrial zone in the area and the remainder will be bought by PLN,” Sudirman said.

The power plant plan was made several years ago but it could not be realized due to licensing and land-acquisition problems.

New power plant complex will be built in two stages

  • First stage of development will begin next year
  • Commercial production is expected to begin by 2018
The complex will need a plot of about 120 hectares in Cilacap. Around 70 hectares would be obtained from the Army’s properties, said Cilacap regent Tatto Suwarto Pamuji. Meanwhile, another 20 hectares was owned by the local administration and the remainder belonged to local citizens in one village.

“Everything is ready. We only lack the location license. However, the coordinating minister said during this morning’s meeting that the license would be followed up,” Tatto said.

With the government’s support, construction of the coal-fired power plant was expected to kick off next year, according to Tatto. 

The government had also settled the mechanism to use the Army’s land for the power plant complex, Indroyono said. 

“As the land belongs to the Army, it means it also belongs to the state. Therefore, the state will pass the title to PLN [the state electricity company]. PLN will then rent the land to the power plant investors.

In a short time, we will discuss the matter with the Finance Ministry,” Indroyono said, adding that the Army chief of staff was also present at the meeting and had agreed to the plan.

Land acquisition has long been a problem for many planned power plant projects in Indonesia. The significant 2,000-MW Japan-sponsored Batang power plant, also in Central Java, has been delayed for years because of a lack of land as local residents have opposed the project.

As of the end of July, the country had 51,980 MW total installed capacity. Given demand growth of about 7 percent per year, the country needs to add 5,700 MW new capacity a year or face a power crisis.

As a number of power plant projects have been delayed, mostly because of land-acquisition problems, Java and Bali are expected to face a power crisis as early as 2016.

Vice President Jusuf Kalla said earlier that the current government expected to add 35,000 MW capacity within its five years in office.

PLN president director Nur Pamudji said earlier that the 35,000-MW power plants would come from ongoing and new projects. He said about 15,000 MW would be supplied by PLN’s power plants and the other 20,000 MW by independent power producers (IPPs).

Monday, February 9, 2015

Electric Shock

NT News, 9 Feb 2015, by Maria Billias

Nightcliff Fitness Works gym owner Seann Scheppard says his power costs have shot up in the past quarter
Nightcliff Fitness Works gym owner Seann Scheppard 
says his power costs have shot up in the past quarter
Territorians hit out at power price hikes with many outraged bills have doubled over last quarter.

TERRITORIANS have hit out at the latest power and water price hikes, with some residents claiming their bills have more than doubled in the past quarter. 

One business owner told the NT News his electricity costs had gone from $9,000 to $15,000 per quarter. Jacana Energy has laid the blame on increased energy consumption over the festive period, but the bills also incor- porate the 5 per cent price hike introduced on January 1. 

Fitness Works owner Seann Scheppard said he had no option but to absorb the costs as a loss so fees were not passed on to members. The gym’s electricity costs have shot up from $2000 to $5000 a month in the past few months. 

“We don’t pass the costs on so we are losing money – it’s a lose-lose situation,” Mr Scheppard said. “You think you are doing OK ... and then you get a bill. It’s quite stressful.” This is the third increase since the NT Government announced the three-year rollout of power price rises in 2012. 

Chief Minister Adam Giles was forced to stagger the fee increases after public outrage at his predecessor Terry Mills’ attempt to slap an outright 30 per cent jump in 2012. But furious Territorians left about 200 acid comments on a public Facebook page when the latest bills rolled in. 

Jen Minotto posted: “Our last one was $476, the one I received the other day was $1078, I’m so angry.” Vicki Price said: “Yep our last bill with 8 weeks of visitors was $1200, this bill is $1600. “I think it’s time to move home, living in the NT is just too expensive.” 

The Power and Water Corporation was split into electricity generation and retail companies on July 1, 2014. Electricity bills now come from Jacana Energy. Jacana Energy boss Stuart Pearce said energy consumption in the Top End was higher in the Wet. “There are many reasons why bills can be a bit higher at this time of year following the build-up or the festive season and each little addition to energy consumption adds up,” Mr Pearce said. “The Territory is one of the highest users of electricity, but enjoy one of the lowest rates in the country.”

Friday, January 23, 2015

Science 2.0 Newsletter January 2015


Science 2.0 Newsletter
Quick Links
Join Our List

Join Our Mailing List




Hidden Magnetic Messages From Space Discovered













There And Back Again: A Uranium Isotope's Journey To The Center Of The Earth








Want to support independent science media? Science 2.0 is not owned by a corporation nor does it receive any government funding. We carry some ads from ad networks but that doesn't even come close to covering the costs. If you like independent science media that is free to read, with no editorial interference or ideological agendas, you can donate here.
Culture       January 12, 2015
Nominate A Top European Influencer For 2015
The Wired 100, now in its fifth year, is an annual celebration of Europe's top digital influencers - the people in the Wired world having the most influence over the sector right now (as opposed to in the past). . Link

  

Physics
Lepton-Flavor-Violating Higgs Decays Fit In With LHCb Anomalies
The CMS Collaboration at the LHC collider has recently measured a non-negligible rate for the fraction of Higgs boson decays into muon-tau pairs. The observation is not statistically significant enough to cause an earthquake in the world of high-energy physics but the matter becomes more interesting if there is a theoretical model which allows for the observed effect, AND if the model is not entirely crazy. Link


Environment
10,000 Shots Of Scotch And Why I Don't Fear Pesticides
One of the biggest struggles in toxicology is creating the correct parameters so you are modeling the real world as closely as possible. It's an enormous task to model the environment with its millions of factors, so controlled studies are done using animals. Link


Education

These semi-serious but mostly joking statements are based on my observations as a student and as a Adjunct Professor at community colleges. Link

Space
Dawn Spacecraft Will Introduce Us to a Strange New World
NASA's Dawn mission is closing in on a mysterious, unknown world in the asteroid belt. Link


Policy

Ted Cruz Overseeing NASA? It Hasn't Looked This Bad Since 2013, Except For 1993, 1973 And 1959

Picture this scenario: A politician is appointed to run NASA who thinks its budget is too high and then half its money and a third of its workforce is on its way to evaporating. Public support for a mission to Mars is nonexistent.

It must be in late 2015, after anti-science Republican Senator Ted Cruz of Texas has control of NASA, if you read science media.

But it was actually 1973, the Golden Age of Space Exploration. Link


Science 2.0 | 10580 N. McCarran Blvd #115-334 | Reno | NV | 89503