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Showing posts with label science. Show all posts
Showing posts with label science. Show all posts

Sunday, January 15, 2023

Binding energy and shell structure of atomic nuclei

 An earlier post shows analysis of NIST data on the atomic masses of nuclei: "Binding Energy of Neutrons and Protons". 

The following chart uses that data to identify the shell structure of nucleons inside atomic nuclei.

The starting point is to find for each nuclide those with the combination of protons and neutrons that have the maximum binding energy. (A nuclide is a nucleus with the same total number of nucleons, no matter how many are protons and how many are neutrons.)

Then the binding energy of adding one further proton or one further neutron to those nuclides is calculated and displayed in the following chart. 

Binding energy of a further neutron or proton to each nuclide which the maximum binding energy of all nuclides with the same number of nucleons

Bands with decreasing binding energies are evident for nuclides with between 88 and 140 nucleons, with between 140 and 208 nucleons, and those with more than 208 nucleons.

Inspecting the specific nuclides at the transitions suggests nucleons are arranged in shells in much the way that electrons are distributed in shells around atoms...

  • The nuclide with 86 nucleons with the greatest binding energy of all nuclides with 86 nucleons is Krypton-86 which has 36 protons and 50 neutrons in its nucleus. The binding energy of a 51st neutron is markedly lower than the binding energy of all preceding neutrons. This is consistent with the "filling" of an available shell by the 50th neutron, and that further neutrons can only be bound in a shell with lower binding energies available. 
  • The nuclide with 116 nucleons with the greatest binding energy of all nuclides with 116 nucleons is Tin-116 which has 50 protons and 66 neutrons in its nucleus. The binding energy of a 51st proton is markedly lower than the binding energy of all preceding protons. This is consistent with the "filling" of an available shell by the 50th proton, and that further protons can only be bound in a shell with lower binding energies available. 
  • The nuclide with 138 nucleons with the greatest binding energy of all nuclides with 138 nucleons is Barium-138 which has 56 protons and 82 neutrons in its nucleus. The binding energy of an 83rd neutron is markedly lower than the binding energy of all preceding neutrons. This is consistent with the "filling" of an available shell by the 82nd neutron, and that further neutrons can only be bound in a shell with lower binding energies available.  
  • The nuclide with 206 nucleons with the greatest binding energy of all nuclides with 206 nucleons is Lead-206 which has 82 protons and 124 neutrons in its nucleus. The binding energy of an 83rd proton is markedly lower than the binding energy of all preceding protons. This is consistent with the "filling" of an available shell by the 82nd proton, and that further protons can only be bound in a shell with lower binding energies available. 
  • The nuclide with 208 nucleons with the greatest binding energy of all nuclides with 208 nucleons is Lead-208 which has 82 protons and 126 neutrons in its nucleus. The binding energy of a 127th neutron is markedly lower than the binding energy of all preceding neutrons. This is consistent with the "filling" of an available shell by the 126th neutron, and that further neutrons can only be bound in a shell with lower binding energies available. 

Wednesday, January 4, 2023

Binding Energy of Neutrons and Protons

 A large amount of data is now available on isotopes of all elements. 

The data includes measurements of the atomic weights of many isotopes of elements - with isotopes that contain many different numbers of neutrons for each element. 

Because nuclear binding energies of neutrons are so large - compared to electron binding energies - the difference on the atomic weights of isotopes can be used to calculate the binding energies of individual neutrons and collections of neutrons. 

For instance, typical binding energies are in the order of 9 million electron volts which is approximately 1 percent of the mass of an isolated neutron. This is equivalent to converting the mass of about 18 electrons into energy. 

For chemical reactions,  binding energies are typically in the order of just a few electron volts. 

The National Institute of Standards and Technology - NIST

The U.S. government agency NIST Physical Measurement Laboratory maintains a table of atomic weights of isotopes of all elements. 

It is available on the NIST web site page "Atomic Weights and Isotopic Compositions with Relative Atomic Masses" by selecting the options "All Elements" and "All isotopes". 

This returns a table with details for over 3,000 isotopes. 

Following are examples of 4 charts prepared by examining neutron binding energies and attempting to identify patterns. 

Each chart use a simplified binding energy scale where 1 represents 2,887 electron volts. On this scale, neutron binding energy values are typically around 3,000 of these units.

Each chart shows binding energy for individual neutrons in two different elements . These are shown on the left axis. 

Note that even-numbered neutrons have slightly higher binding energies than the odd-numbered neutrons, and the binding energy gradually declines as increasing numbers of neutrons are added while the number of protons in the nucleus is kept constant. With the addition of protons, the neutron binding energies are higher.

The sum of the binding energies of selected neutrons are shown on the right axis.


Chart 1

Binding Energies of Neutrons in Yttrium which has 39 Protons and Niobium which has 41 Protons.


Chart 1 shows that the neutron binding energies drop after the first 50 neutrons in each nucleus, and dip slightly after the first 56 neutrons.

In Yttrium, the sum of the binding energies of the 8 neutrons from 53 to 60 is exactly the same as that of the 8 neutrons from 57 to 64 in Niobium. This is with an increase of two protons from Yttrium with 39 protons to Niobium with 41 protons.

Chart 2

Binding Energies of Neutrons in Yttrium which has 39 Protons and Indium which has 49 Protons.

 

Chart 2 again shows that the neutron binding energies drop after the first 50 neutrons in each nucleus, and dip slightly after the first 56 neutrons in Yttrium - that has 39 protons. This dip does not appear in Indium that has 10 additional protons in its nuclei. 


In Yttrium, the sum of the binding energies of the 12 neutrons from 58 to 69 is exactly the same as that of the 6 neutrons from 58 to 63 in Indium. This is with an increase of ten protons from Yttrium with 39 protons to Indium with 49 protons.

Chart 3

Binding Energies of Neutrons in Bromine which has 35 Protons and Indium which has 49 Protons.


Chart 3 again shows that the neutron binding energies drop after the first 50 neutrons in each nucleus. 


In Bromine, the sum of the binding energies of the 20 neutrons from 38 to 57 is exactly the same as that of the 20 neutrons from 58 to 77 in Indium. This is with an increase of fourteen protons from Bromine with 35 protons to Indium with 49 protons. 

Chart 4

Binding Energies of Neutrons in Gallium which has 31 Protons and Arsenic which has 33 Protons.

 Chart 4 again shows that the neutron binding energies drop after the first 50 neutrons in each nucleus.

 
In Gallium, the sum of the binding energies of the 16 neutrons from 41 to 56 is exactly the same as that of the 8 neutrons from 33 to 40 in Arsenic. This is with an increase of two protons from Gallium with 31 protons to Arsenic with 33 protons.  

 

Total Binding Energies of Nuclei

 The preceding charts are examples of the incremental binding energy of adding one or more protons, and one or more neutrons to a selected nuclei / isotope. 

In addition, the NIST data can be used to examine patterns in the total binding energy of atomic nuclei. 

The following chart shows the total binding energy of nuclei that contain 88 nucleons (all available combinations of neutrons and protons in a nucleus where the total is 88). 

The maximum binding energy is the combination of 38 protons and 50 neutrons. 

This is a stable isotope of Strontium. None of the other combinations of 88 protons plus neutrons are stable. They are not found in nature. 

Chart: Total binding energy of all isotopes containing 88 nucleons

Binding energy of isotopes with 88 nucleons

If the maximum binding energy of each isotope with a given number of nucleons is plotted, the resulting graph resembles a smoothly increasing concave function. 

One of the points on the curve is for the isotope of Strontium with 88 nucleons - this is the isotope with 88 nucleons that has the maximum binding energy of all isotopes with 88 nucleons. 

The following chart contains a second plot that shows the variation of maximum binding energy of all isotopes from a perfectly smooth concave function. It reveals an orderly and structured arrangement of the total binding energies of nuclei. This orderly structuring is similar to what is seen when individual nucleons are added sequentially to a nucleus, but is also in some ways independent of that pattern. 

Chart: Maximum Total Binding Energies of all Nuclei with equal numbers of nucleons and Variations from a smoothed function fitted to that plot of maximum total binding energies

Maximum Binding Energies of Isotopes with equal numbers of nucleons

 

If the actual maximum binding energies precisely followed the smoothed function fitted to the curve then the variation between the actual binding energies and that smoothed function would be a horizontal line - as can be seen for nucleons with 230 to 250 nucleons.

Tuesday, July 21, 2020

Innovation vs Coronavirus

There is a risk of covid-19 infections spreading in enclosed spaces via microdroplets.
Covid-19 transmission occurred through the air in a crowded and poorly ventilated space
Covid-19 transmission occurred through the air in a crowded and poorly ventilated space

Coronavirus spreads through the air as aerosol

The letter, led by internationally recognised air quality and health expert Lidia Morawska from the Queensland University of Technology, makes an appeal for public health organisations like the WHO to address the "overwhelming" research on the dangers of microdroplets.
Technology and innovation may assist making enclosed spaces - buses, trains, cafes, and so on - safer.
  • An air filtration unit can remove microdroplets from air.
  • Fitting the air filtration unit with an anti-viral mechanism, such as an ultraviolet lamp may enhance its ability to remove coronavirus contamination.
  • A sensor capable of detecting coronavirus particles installed in the air intake of an air filtration unit would allow it to serve like a "smoke detector" - warning people of the need to evacuate a contaminated room. 

Sunday, June 14, 2020

Discussion of Hydrogen - Boron 11 fusion

University of New South Wales researchers led by Emeritus Professor Heinrich Hora have made important breakthroughs recently in developing clean nuclear energy technology.
When a proton (a Hydrogen nucleus) fuses with a Boron-11 nucleus it produces 3 alpha particles (Helium nuclei).
That's it. No radioactive fuels. No radioactive waste.

See "Pioneering technology promises unlimited, clean and safe energy" for a recent University of New South Wales report.
Hydrogen Boron-11 fusion
Hydrogen Boron-11 fusion


April 4, 2011: Overturned scientific explanation may be good news for nuclear fusion

"Researchers have been developing reactors to slam hydrogen at high speeds into boron-11, a collision that yields high-energy helium nuclei, or alpha particles. Those alphas then spiral through a tunnel of electromagnetic coils, transforming them into a flow of electrons, or electricity."

June 12, 2020: Ultra-Fast High-Precision Metallic Nanoparticle Synthesis using Laser-Accelerated Protons

The technique of using high-energy lasers to accelerate hydrogen (aka protons) is finding wide application beyond fusion with Boron11.

Friday, February 14, 2020

The shape of the cosmos

Serrendipity in viewing the following three videos on YouTube in this sequence conjures an unlikely but curiously intriguing thought...

1. The 1995 Hubble photo that changed astronomy



2. Why does light slow down in water?


3. A Miraculous Proof (Ptolemy's Theorem) - Numberphile


The first video shows images of the early universe as it existed over 14 billion years ago.
Hubble image of the Big Bang
Hubble image of the Big Bang

The second video provides a possible explanation for why the light from 14 billion years ago is only now arriving at the Hubble Space Telescope... namely that the light may have travelled quite slowly through the material existing in the early universe (just as it travels more slowly through water) while the outer parts of the expanding universe zipped off at a faster pace.

The third video gives a perplexing suggestion for the Hubble Space Telescope seeing the early universe no matter which direction it is pointing.

If the Hubble Space Telescope pointing in one direction viewed the early universe as a small bubble, then it might have been that when pointed in the opposite direction it would view the outer edges of the universe that had travelled ahead of the Milky Way galaxy as the universe expanded.

Curiously the Hubble Space Telescope viewed the earliest components of the universe no matter which direction it pointed.

The third video describes a process for creating one specific isomorphism of a geometrical structure.
"Reflection" - one type of transformation
"Reflection" - one type of transformation - "it will keep his elephant-ness"

"our inversion is a completely different animal"
"our inversion is a completely different animal"
  • Points on the transform circle go to themselves. Points outside the circle go to points inside the circle. 
  • Lines through the centre of the transform circle go to themselves. Lines not through the centre become circles through the centre.
    Lines through the centre go to themselves
    Lines through the centre go to themselves
  • Circles inside the transform circle but not through the centre go to circles that are outside the transform circle. 

The latter mapping for circles inside the transform circle -in particular for those that are increasingly near to the centre- go to ever more distant circles outside the transform circle.

This is a description that uncanningly matches Hubble Space Telescope's images of the early universe.

Instead of seeing a miniature bubble in only one direction that represents the early universe, what the Hubble Space Telescope sees is a vast uniformly distant bubble that light has travelled for 14 billion years from all directions to reach it.

Perhaps the Hubble Space Telescope's image is of Aladdin's Shoe.
The view containing the Elephant has been subjected to an abstract mathematical transformation?

Saturday, March 16, 2019

Clean nuclear energy with a simple electricity output stage

University of New South Wales researchers led by Emeritus Professor Heinrich Hora have made important breakthroughs recently in developing clean nuclear energy technology.
When a proton (a Hydrogen nucleus) fuses with a Boron-11 nucleus it produces 3 alpha particles (Helium nuclei).
That's it. No radioactive fuels. No radioactive waste.
Hydrogen Boron-11 fusion
Hydrogen Boron-11 fusion

And another result: For each 11 grams of Boron-11 (one mole) converted to Helium, the energy produced is around 230 megawatt-hours.

At the level of individual nuclei, the mass of the three Helium nuclei produced is about 17 electron masses less than the mass of the Hydrogen nuclei (a proton) and the Boron-11 nuclei that undergo fusion to create them. It is this "missing" mass that appears as energy. Specifically this energy is kinetic energy imparted to the Helium nuclei.

Laser-boron fusion now ‘leading contender’ for energy
"The fuels and waste are safe, the reactor won't need a heat exchanger and steam turbine generator, and the lasers we need can be bought off the shelf," says Warren McKenzie, managing director of HB11, which owns the patents to the new technology.

When coal is used to fuel a high-efficiency low-emission "HELE" ultra-supercritical coal-fired power station, carbon dioxide emissions are 900 kilograms per megawatt-hour. The amount of carbon in the coal needed for each megawatt-hour of electricity generated is 900 x (12 / 44) kilograms. That is coal containing 245 kilograms of carbon is burned for each megawatt-hour.

To generate 230 megawatt-hours of electricity in a "HELE" coal-fired power plant coal containing over 56 tonnes of carbon would need to be burned. It would be converted into almost 210 tonnes of carbon dioxide.

Yes. 
That's right. 
56 TONNES of carbon vs 11 GRAMS of Boron-11 for the same electrical energy output.

Coal power plants have another serious handicap. The energy produced when coal is burned is heat energy. Extremely high pressure boilers and turbines are required to spin large generators to convert the heat energy into electricity.

With proton-Boron-11 fusion, the energy produced is in the form of fast-moving positively charged Helium nuclei. This kinetic energy of charged particles can be converted directly into electricity. There is no need for steam boilers, turbines and generators.
While the nuclear reactor is being developed, the technology to create electricity from fast-moving charged particles can be done in parallel. For instance, the ion propulsion test facility at the Australian National University could produce streams of ionised gases to use in developing the electricity production technology.
Professor Christine Charles is Head of the Space Plasma, Power and Propulsion laboratory at the Australian National University.
Professor Christine Charles is internationally recognised for her research on ion acceleration in expanding magnetised plasmas and its applications to a new generation of space engines and advanced material processing.



Update - 5 July 2019 

Progress in research in seemingly unrelated fields may lead to sudden advances, solving tasks that are steps to manufacture small commercial laser-driven fusion electricity power modules.

From this article "Self-Torque: Physicists Discover New Property of Light" on 1 July 2019 for instance -
In 1992, it was realized that light can also possess orbital angular momentum (OAM) when the spatial shape of the beam of light rotates — or twists — around its own axis.
...
In order to realize an entirely new property of light, manifested as a time-varying OAM along the light pulse, JILA physicist Kevin Dorney, University of Salamanca’s Dr. Laura Rego and their colleagues exploited the quantum physics inherent to the high harmonic generation (HHG) process.

“To create that high harmonic generation with light, an intense, femtosecond laser pulse is upshifted to high frequencies of the driving laser by essentially creating a nanoscale radiating antenna from an atom that is in the process of being ionized,” they explained.

“When properly phase-matched, bright, coherent laser-like beams can be generated that span from the extreme ultraviolet (EUV) to the soft X-ray regions of the electromagnetic spectrum.”

Thursday, July 12, 2018

Coal burns up research millions

If an industry needs to separate CO2 from different sources the first place to look is existing suppliers and projects that use their technology.

Reinventing the Wheel

Reinventing the wheel
"...the investment in research programs will yield industry
applicable technologies and methodologies in the near term."

Australian governments are spending millions to find out how to separate CO2 from different sources. This process is commonly referred to as "reinventing the wheel".

Why this is so remains an unexplained mystery.

"...our capture research has also made progress on several fronts. CO2CRC won a competitive $1.2 million grant from the NSW government’s Coal Innovation Fund to develop cost-effective carbon capture technology at the Vales Point power station in NSW. The plant has been relocated from the closed Hazelwood power station in Victoria to Vales Point and is currently being modified to use both solvent and membrane technologies. The funding enables us to combine the advantages of both solvent absorption and membrane gas separation methods of capturing CO2, while overcoming the drawbacks of both technologies.

Capture projects were also significantly enhanced in October when we installed our proprietary capture skid at the Otway National Research Facility. The capture plant has been designed for use in offshore natural gas applications, with varying percentages of CO2 content. It has been made to be robust, small and efficient, and will also applicable to different capture requirements in the future.

These developments are the result of our deep commitment to cutting-edge research. In 2016-17 we extended our research base through the opening of several new Australian CCS Research Laboratories Network (CCSNet) facilities.

In September 2016, we opened new capture, CCS modelling, and storage laboratories at The University of Melbourne.

The $7.56 million facility was opened just 12 days after the Minister for Infrastructure and Transport, the Hon Darren Chester MP, opened CCSNet’s $2.3 million analytical laboratory at Federation University.

And, in November, the Minister for Education and Training, Senator the Hon Simon Birmingham, opened our $5.04 million storage research facilities at the Australian National University.

As CCS research gains momentum, we also remain focussed on ensuring government and key decision makers understand the value that CCS has to Australian emissions reduction and national energy security. Our detailed and costed retrofit studies, submissions to government and presentations to senior decision makers were well received by governments.

With the commitment from staff, the collaboration of our research partners and the support of our members and the community, CO2CRC has reached a pivotal point where the investment in research programs will yield industry applicable technologies and methodologies in the near term. Thank you for sharing our vision for CCS.

Tania Constable
Chief Executive Officer
CO2CRC Annual Report 2016/17

Monday, February 12, 2018

Wastewater gone without a trace

Wastewater treatment service business typically make claims  like -
"Our focus is on fit-for-purpose water re-use to ensure that your project delivers on your expectations."
A new business model could make a quite different claim -
"Our focus is on gone-without-a-trace wastewater conversion to renewable fuel."
Integrated biodiesel and biogas production from microalgae
Integrated biodiesel and biogas production from microalgae

Microalgae convert water and carbon dioxide into oxygen and chemical compounds of carbon, hydrogen and oxygen.

Some bacteria convert chemical compounds of carbon, hydrogen and oxygen into methane and carbon dioxide.





The above two processes results in the decomposition of water molecules  and carbon dioxide molecules and their reassembly into methane, oxygen and carbon dioxide molecules. For each 2 water molecules and 2 carbon dioxide molecules entering the process,  1 molecule each of methane, oxygen and carbon dioxide exit.

When 1,000 litres of wastewater are reassembled, the methane produced has an energy content of about 22 gigajoules.

While the value of 'fit-for-purpose" processed wastewater is very low, methane has a wholesale value around $10 per gigajoule and a retail price 2 - 6 times the wholesale value.



Another process uses renewable electricity that is generated when demand is low to produce gas from crop waste, municipal waste, sawdust, etc in a plasma gasifier...




Friday, December 29, 2017

As the Arctic gets warmer, winters get colder

Published at -
https://www.popsci.com/are-we-doomed-arctic-winters-america on November 14, 2014 and
https://www.popsci.com/polar-freeze on July 10, 2017.


Are We Doomed To Arctic Winters In America?

Scientists Square Off On The Coming Freeze


Frigid Friday

Let's all move to Miami.

National Oceanic And Atmospheric Administration

There's an unwelcome guest on your doorstep, America.

It comes from the north, dragging frigid air and awful commutes like a terrible shroud over the continental United States, from the Rocky Mountains all the way to the Atlantic. While the East Coast saw temperatures about 10 degrees below average Friday, snow hit much of the Midwest following a 40 degree drop over just a couple days in Chicago, and a region stretching from Denver to Montana saw sub-zero chills and record lows.

This morning, in the stairwell of an apartment building, even New York City's relatively mild mid-30s weather prodded a father into a shouting match with his weeping child: "But I don't want to go to school today! It's too cold to go outside!" "Put your coat on, now!" And in the halls of climate research centers and weather stations across the nation, the cold snap is spurring a more technical, but no less divisive debate — one that matters to millions of Americans who remember the last awful winter: Is this the new normal?

Ice, Alaska, And Damned Typhoons

Pacific Blast

Typhoon Nuri joins the most powerful storms on record in the Bering Strait.

National Oceanic And Atmospheric Administration

With nearly two weeks left before Thanksgiving, this should be a time for tweed and brisk walks through colorful fallen leaves (the autumn the Lands End catalog promised us). Instead, if you live anywhere from Chicago to Appalachia you've likely found yourself breaking out the Gore-Tex for a slog through accumulating snow and ice, with more likely coming this weekend, and its all because of a storm on the other side of the world.

Typhoon Nuri formed in the West Pacific and surged north, peaking with sustained winds around 180 miles per hour — one of the strongest typhoons or hurricanes of the year. As it moved past Japan and into the Arctic it weakened, but its powerful remnants still delivered tropical storm conditions to Alaska's Aleutian Islands, Eastern Russia, and the Bering Strait.

You'd think a mega storm careening off into the underpopulated Arctic would be a kind of best-case scenario, and in many ways it is. There are fewer houses and people out in those cold places, and local damage was minimal. But those sparse communities share air with the jet stream (or "polar vortex"), a muscular current of air that circles counter-clockwise high in the atmosphere between the warmer air masses of the mid-latitudes and the much colder northern reaches.

Several scientists who disagree on most other issues surrounding polar vortex events (including whether "polar vortex" is an acceptable or ridiculous name for these Arctic air surges) came up with just about identical analogies for what happened when Nuri slammed into the jet stream: a taut rope snapping. All that frozen air normally locked in a tight spiral snapped south between an air pressure ridge over the Rockies and Greenland. The resulting arctic wave sunk temperatures far below average along the American continent, and they'll likely remain low for a couple of weeks.

Polar America

Martin Hoerling, a scientist (and according to some of his colleagues, a contrarian) studying climate change with the National Oceanic and Atmospheric Administration (NOAA), says fears of frozen winters future are fair but unfounded.

He says, "If I were a member of the public I'd be thinking, 'Oh God, I barely survived the last winter and now it's getting cold again? Is this what I can expect from now on?'" But Hoerling says this pattern of typhoon-induced cold fronts is not new, it's just been given the new, scary, "polar vortex" branding.

If anything, he says, the warming world will see fewer extreme weather shifts because the Arctic and mid-latitudes will be nearer in temperature.

"If I were a member of the public I'd be thinking, 'Oh God, I barely survived the last winter and now it's getting cold again? Is this what I can expect from now on?'"
But Jennifer Francis, a researcher with the Institute of Marine and Coastal Sciences at Rutgers University who studies the impact of Arctic warming on the global climate, disagrees. Her research predicts that as Arctic warms (and it is warming extraordinarily quickly) the jet stream will weaken and narrow. "When you have a strong jet stream it's like a thick rope. You can give one end a tug and not much happens." But as it weakens, she says, it's more like a string. A shake (or a typhoon) will send waves all along its length, causing the Arctic monster to move south more often.

While Hoerling dismisses Francis's research as "pure conjecture", and points to early failures to verify her predictions, other meteorologists and climatologists look at "Weakening of the stratospheric polar vortex by Arctic sea-ice loss" and recent studies and are more convinced.

James Overland, also of NOAA, says he leans toward Francis's view. "In the last five years we've seen more of the wavy [jet stream] patterns in January and December than we did before," he says. In his view, it makes sense that a warmed Arctic would break down the jet stream's regular tight ellipse.

Francis acknowledges that her research does not fully account for everything that will impact this winter and those that follow. "All these are pieces to the puzzle," she says.

The debate might seem academic, but its consequences go far beyond discomfort. Last year's harsh winter cost the economy billions, and revealed just how unprepared much of the country is for even slight shifts in storm patterns. More winters like the last could mean more deaths, widespread damage, and economic sluggishness.

So, About January

All other things being equal, meteorologists expect a weak but warming El NiΓ±o effect to render this winter a relatively mild one, though forecasters have lowered the probability from 65 to 58 percent at last measure.

Hoerling, along with most other researchers, says there's no reason to expect the current cold snap to portend a trend this season. But Francis isn't so sure.

Last year's harsh winter cost the economy billions, and revealed just how unprepared much of the country is for even slight shifts in storm patterns.
"It all depends on what happens with El NiΓ±o — if it does form, what we're seeing right now will probably end," she says. But she says it looks more and more likely that won't happen. "The pattern of surface temperature in the North Pacific look a lot like last winter."

In other words, let's hope that unwelcome guest packs up and leaves for good. But if it comes back, bringing with it plunging mercury, snot-icicles, and general misery, you'd best be ready. Shiver


As the Arctic gets warmer, our winters get colder

And our plants take a hit.



As the arctic warms, it alters weather patterns leading to more frigid winters in North America.
U.S.-Canada Fourth Joint Mission To Map the Continental Shelf in the Arctic Ocean
U.S.-Canada Fourth Joint Mission To Map the Continental Shelf in the Arctic Ocean

US Department of State


In the winter of 2015, New York City’s Hudson River froze—a rare occurrence. Prior to the 2000s, the record shows that the Hudson froze in 1720, 1780, and 1821—a period that overlaps with the so-called Little Ice Age, when the Northern Hemisphere was cooler overall. But since the turn of the century, the lower Hudson has frozen not once, but twice: in 2015 and 2003. Meanwhile in the Midwest, the National Oceanic and Atmospheric Administration (NOAA) recorded the winter of 2013-2014 as one of the region’s coldest on record. That is the year, according to Google Trends, that the terms “Polar freeze” and “Arctic freeze” entered the public lexicon.

We didn’t use those terms before because, as a new study released today in the journal Nature Geoscience highlights, we didn’t need them. More intense winters (and their increased frequency) are a new phenomenon courtesy of a warming Arctic.

If the idea that both very cold and very warm winters can be linked to climate change doesn’t sound intuitive, that’s because it isn’t. To figure this out, researchers from Pohang University of Science and Technology in South Korea and from the South University of Science and Technology of China analyzed a number of datasets, beginning with those related to something called teleconnection patterns.

It wasn't until 2013 that we started to talk about Polar Freezes.

Google Trends


Climate anomalies don't happen in a vacuum, but are in fact related to each other even at great distances. The atmosphere acts like a giant, swirling pinball machine—changes in one place can trigger changes in another. We call those weather relationships teleconnections.

The El NiΓ±o-Southern Oscillation is perhaps the most famous teleconnection, and though we in the United States tend to experience El NiΓ±o directly as warmer weather, the weather effects are caused by changes in the atmosphere. In the case of El NiΓ±o, the atmospheric action is what’s known as the Southern Oscillation, a periodic change in atmospheric pressure across the Indonesia Tropical Pacific. This change in pressure triggers what we think of as El NiΓ±o type weather.

In studying teleconnections, the researchers recognized that as the Arctic (including Alaska and East Siberia) gets warmer, North America gets cooler in winter—a temperature change strongly correlated to shifts in atmospheric patterns. That shift in conditions, the authors found, also leads to less precipitation in the South-Central portion of the United States.

“The link found between Arctic warming and continental cooling is probably not a simple cause–effect mechanism,” writes Ana Bastos, a researcher at the Laboratoire des Science du Climat et de l’Environement, in an op-ed published alongside the study. She goes on to note that the effect is likely to vary between different regions, and that a closer look could make the relationship between these climate shifts more clear.

In addition to looking at how changes in the Arctic shift weather, the researchers also looked to see what those changes were doing to plant growth. And the consequences for agriculture don't look great. Cold winters and springs lead to biological stress, causing problems in plants that linger even as the temperature warms.

Impacts of Arctic warming on United States crop yields. Light brown and green indicate non-significant states and white means undefined states due to the lack of crop-yield data.

Nature Geoscience


This isn’t just bad for farmers, it’s bad for anyone who wants to mitigate the effects of climate change, which is itself driving much of the Arctic warming. We depend on plants to absorb carbon emissions—they're what's called a carbon sink. So if climate change warms the Arctic, and that triggers weather changes that cool down North American winters and dry out our farms, the resulting agricultural problems could actually make the Arctic warm even more quickly.

This study isn’t the first to find that shifts in teleconnections are leading to odd weather elsewhere. The 2010 heatwaves that hit Russia, for example, and which were found to be caused by climate change, were also linked to severe flooding in parts of India rarely subjected to rain. The message is clear: By messing with the climate, we’re fundamentally changing the weather systems we’ve come to depend upon for human survival.

Saturday, February 6, 2016

Would you be surprised if one day energy was free?

Part 1 - Canberra August, 2004

"I've always been really interested in recreating space phenomenon in the laboratory. It's very difficult to measure in space to measure the aurora although it is a true wonder in seeing these lights in the sky. But to simulate this in the laboratory, to do experiments on it and then try and understand what is happening I think for me is one of the greatest joys that we've been given", said Dr Rod Boswell.

Aurora - atmospheric plasma

First you make the plasma by zapping a gas with radio waves - "microwaving" it. The atoms change into electrically charged particles called ions. Cut the end of the tube and the ions all shoot out, creating thrust - plasma thrust.

"This is Wombat. It's called wombat because it's got four legs and sort of looks like a wombat. You can see here we create a plasma, this is the glowing gas you can see in the end there. So the plasma's created here then moves into space. And if you look in there, ah, it always amazes me. There's this blue column of plasma which is shooting out from the plasma source," Rod explained.

Wombat - plasma generator research device

Rod made quite an impression around the world with his Wombat plasma generator. NASA took some of his ideas to design tiny satellite guidance thrusters.

Anxious to find new ways to make plasma thrusters work better, Rod assembled a team of young physicists, and encouraged an atmosphere of ideas and creative thought.

"I came here to ANU because I thought that this is one of the top laboratories in the world. The environment is just perfect and it's really good for creativity," explained Dr Christine Charles.

Professor Christine Charles
Professor Christine Charles
Head of the Space Plasma, Power and Propulsion Laboratory
Australian National University
Christine, freshly arrived from France, soon became inspired by Rod's enthusiasm for plasmas, and for the forces in the universe that generate them.

Rod had recently commissioned a new, improved version of wombat, and Christine was eager to try it out, to see if she could, amongst other things, recreate an aurora in the lab. One day, impatient for results, Christine decided to play with the settings. She was amazed with what happened next.

"I'll show you. Normally this is standard plasma, but on the day, instead of doing what everyone does which is turn the knob on, turn the power on, and see what happens, I did the opposite. I turned the power down and I reduced the flow down. So then you need to increase the magnetic field to be able to contain it. So you do that, you make the measurements with the ions... Look at this, there it is. The hot ions, the plasma is suddenly accelerating, all by itself. It appeared to be in free fall, travelling much faster then I'd ever seen before. And I kept getting this result, and I thought, oh, this is like, oh! What's happening!" Christine recalled.

"The plasma behaves like water tumbling over a cliff, getting faster as it drops. And, just like an aurora, it seems that the plasma actually makes the 'cliff' - all by itself. It's almost magic."

"What Christine found is that under certain conditions instead of just flowing out smoothly it creates this jump, and the ions fall down this, and it's like having two electrodes that accelerate the ions like in an accelerator, but there are no electrodes! The plasma itself forms an acceleration mechanism. It's actually a wonder," said Rod.

Monday, January 18, 2016

Power stations, Engines, Air Conditioners Fuels Cells, Batteries and more

Innovative design can be spurred by scientific understanding of energy storage and transformation.

This diagram represents current scientific understanding of how energy may be stored and transformed.
Power stations, Engines, Air Conditioners Fuels Cells, Batteries and more

A power station can theoretically convert 10,000 joules of thermal energy at 1200 degrees Kelvin into 7,500 joules of electrical energy and 2,500 joules of thermal energy at 300 degrees Kelvin.

It is also theoretically possible to decompose some chemical compound into its constituent elements with 10,000 joules of thermal energy at 1200 degrees Kelvin and produce 7,500 joules of electrical energy and 2,500 joules of thermal energy at 300 degrees Kelvin in a fuel cell that recombines those elements into the original chemical compound.

If it is cheaper and more reliable to construct a machine that operates at a temperature of just 900 degrees Kelvin instead of 1200 degrees Kelvin, then this machine could theoretically decompose the chemical compound into its constituent elements with 2,500 joules of electrical energy and 7,500 joules of thermal energy at 900 degrees Kelvin.

It is not necessary to view batteries as the only type of device that can store electrical energy:
At some later time the decomposed elements could be used to produce 7,500 joules of electrical energy and 2,500 joules of thermal energy at 300 degrees Kelvin in a fuel cell that recombines those elements into the original chemical compound.
The graph above is a representation of scientific knowledge from which these observations can be made.

Mathematics permits this simple geometric model to be created from three separate scientific models:
  • Carnot's equation for efficiency of heat engines.
  • Nernst's equation for electrochemical reactions.
  • Gibbs-Helmholtz's equation for chemical reactions.








Sunday, November 22, 2015

Energy storage and storing a decrease in entropy

1/ Power an air compressor with 13.38 kWh of electric energy to produce heating for a household's daily hot water consumption. The electric energy is converted to heat energy at about 60°C to produce 270 litres of hot water at 55°C and compressed air cooled to 25°C and 8 atmospheres.
See the spreadsheet below for calculations of thermal energy needed to supply 270 litres of hot water per day for a household or business.

2/ The compressed air produced at 25°C and 8 atmospheres (absolute) pressure may be used for driving compressed-air tools.
See the spreadsheet "AirCompressor" for the calculation of the energy used by the compressor and the volume of air it compresses.
Constant-Pressure Compressed Air Accumulator

3/ The compressed air instead may be used in a solar-air turbine to deliver 24.55 kWh at 100% thermal efficiency by compressing it adiabatically to 32 atmospheres before heating it further with an external thermal energy source at constant pressure then expanding it adiabatically before finally outputting it at 25°C and 1 atmosphere pressure.
See the spreadsheet "AirHeatEngine" for the calculation of the conversion of heat energy to 24.55 kWh electrical energy at 100% conversion efficiency with the compressed air that was produced while providing a household or businesses daily hot water requirements.

Note that while the conversion of thermal energy to electrical energy can achieve an efficiency of 100%, the total efficiency takes into account the 13.38 kWh consumed to produce the compressed air. The overall efficiency for this model is (24.55 - 13.38) / 24.55 = 45.5%.

spreadsheets

Monday, October 5, 2015

Treasury officials' blinkered view of innovation

"Australia's Economic Policy Challenges"

as seen through the eyes of

John Fraser | Secretary to the Treasury | 27 February 2015

I will spend a few minutes reflecting on the trends that we're seeing in the three drivers of long term economic growth — population, participation and productivity — and the implications for policy.

...the first key driver of economic growth in the medium term is population.

In recent years, Australia's population growth has been amongst the fastest in the developed world, driven by migration.

A growing population can be a source of dynamism for the economy.
The blinkered leading the blinkered
The blinkered leading the blinkered

It provides a larger domestic market for business, increases the size of the labour force and facilitates the injection of new ideas.

But it also places additional demands on government budgets in areas such as infrastructure, health and education.
...

The Government has commissioned a number of policy reviews that will recommend ways to enhance Australia's economic prosperity.

Making the most of these reform opportunities is essential, where three areas stand out as priorities for raising Australia's productivity performance.

The first is tax reform.

Studies have consistently shown that tax reform offers one of the largest policy opportunities to increase incomes and living standards.
...
Tax reform can promote strong investment and encourage workforce participation.

Our company tax rate is high by international standards.
...
A second priority is continuing to modernise the workplace relations system.

Workplace regulation has been progressively and substantially reformed in recent decades.

A more flexible workplace relations system that supports the economy will help Australia respond to the challenge of lifting productivity growth.
...
A third priority area for structural reform is driving greater competition in goods and services markets.

Ian Harper proposes that we apply competition law and a new set of competition principles to all purchasing activities of government such as health, education and aged care.

Even small improvements here, where government has a large footprint and where Australia's population will impose greater demands on health and aged care, can deliver big benefits over time.

Beyond the blinkered economics policy advice from Treasury - that must surely be overdue for a dose of its own advice on the value of fresh ideas inside Treasury itself - "a growing population can be a source of dynamism" - there are of course other places to look  for policy ideas for growing an economy.
For instance:
  1. "The effect of our poorly planned mental health system is a massive drain on the wellbeing of people and families, and on Australia’s productivity and economic growth. The economic cost of mental ill-health is enormous. Estimates range up to $28.6 billion a year in direct and indirect costs, with lost productivity and job turnover costing a further $12 billion a year - collectively $40 billion a year or more than two per cent of GDP,” Prof. Fels said. (See National Review of Mental Health Programmes and Services Report released, 16 April 2015)
  2. "The use of Information Technology in the production of goods and services has had a strong influence on productivity and economic growth in industrial and in newly industrialized countries... Information communications technology (ICT) is not only one of the fastest growing industries – directly creating millions of jobs – but it is also an important enabler of innovation and development." (See  Five ways technology can help the economy , 11 April 2013)
  3. "The International Energy Agency (the IEA) believes that the world needs a clean energy revolution in order to break dependence on fossil fuels. Such a revolution would enhance global energy security, promote enduring economic growth and tackle environmental challenges such as climate change. It would break the long-standing link between economic growth and carbon dioxide (CO2) emissions." (See  Clean Energy Technologies )

Thursday, July 16, 2015

Wind turbines complement coal, natural gas and liquid fuels

New German technology converts 2 gigawatt-hours of off-peak electricity from wind turbines into hydrogen in its first year of operation. (See E.ON Wind Energy Gas Storage GmbH)

For private households the “Wind-to-Hydrogen” product can be obtained as a mix of 90 % natural gas and 10 % regenerative hydrogen.

This technology competes with battery energy storage. The commercial value of hydrogen and oxygen from off-peak wind energy has to be weighed up by investors against the cost of storing this off-peak energy in batteries for resale at a higher price during peak periods.
Wind farm energy to hydrogen and oxygen
Wind energy to hydrogen and oxygen

There are opportunities to expand the market for hydrogen and oxygen from low-cost off-peak electricity generated by wind farms:
  • Oil refineries consume a vast amount of hydrogen to produce transport fuels. At present refineries use natural gas to make hydrogen.
  • Oxygen from wind turbine electrolysis units can cut the reliance on air separation plants making oxygen for use in coal gasification. (The process of gasifying coal and municipal or crop waste with pure oxygen also lowers the cost of separating carbon dioxide - itself a valuable product in the emerging algae-oil industry and traditional markets such as fertiliser manufacture.)

The Purox process was developed by Union Carbide in the early 1970's

Air may be cheap but from a thermal-efficiency perspective it's expensive because only one fifth of air is oxygen with nitrogen forming the remaining four fifths. Gasifiers that use air as the oxidizing gas have to heat up five times as much air than one using pure oxygen as the oxidizer and separating carbon dioxide from large volumes of nitrogen is an expensive process.

In the mid-1970's pure oxygen was produced by the fractional distillation of liquid air, a process which is energy intensive and technologically challenging.

Monday, July 13, 2015

The coal industry needs better advice from business analysts and chemists

While the coal industry invests in political lobbyists and advertising agencies its future grows dim.

Sales volume is not a measure of success

Producing ever increasing volumes of any commodity at steadily falling prices is a well-trodden path to oblivion. The Australian fine merino wool industry has "been there, done that."

Australian thermal coal price


Peabody Energy share price chart

Innovation that reduces efficiency is misguided

"Leading edge" super-critical coal-fired power stations are far less efficient than modern gas-fired power stations. This technology is obsolete having been overtaken by rival technologies.


How an industry can lift the return per kilogram of carbon

To remain viable an industry needs innovation that lifts the return per unit of production. Coal gasification is a step in this process. The energy market is not the only game in town.

Farming needs stable supplies of fertiliser, one of which is urea. Urea is manufactured from carbon dioxide, sells for around $350 per tonne and has 200 kilograms of carbon in each tonne (ref: WebQC.org Chemical Portal).

Contrast this with thermal coal that sells for around $80 per tonne and has 610 kilograms of carbon in each tonne (ref: Coal conversion statistics.)


Urea price per tonne chart


Urea is made from carbon dioxide



The coal industry doesn't appreciate the commercial potential of carbon dioxide.

Algae can manufacture 1,000 kilograms of edible oil that contains about 750 kilograms of carbon from water, carbon dioxide and sunlight. Algae consume 2.75 tonnes of carbon dioxide to make a tonne of edible oil. Prices range from $1,000 to $5,000 per tonne.
"Nutraceuticals are various products that range from isolated nutrients, dietary supplements and herbal products, to processed foods and beverages. With the correct blend of enriched nutrients using custom selected micro-algae as a source, Algae.Tec is able to deliver specialty high value oils, antioxidant-rich products and supplements, as well as edible oils and pigments, which provide a variety of health benefits. This approach is a sustainable alternative to current feedstock options, for items such as Omega-3s, which are derived from static fish supplies. The Algae.Tec advantage provides both a quality and consistent product that meets the needs of many nutraceutical applications." (Source: Algae.Tec website)

Edible oil price chart